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The manganate and permanganate ions are tetrahedral, due to :

(1) The $\pi$-bonding involves overlap of p-orbitals of oxygen with d-orbitals of manganese

(2) There is no $\pi$-bonding

(3) The $\pi$-bonding involves overlap of p-orbitals of oxygen with p-orbitals of manganese

(4) The $\pi$-bonding involves overlap of d-orbitals of oxygen with d-orbitals of manganese
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The d and f block elements, some important compounds of transition elements

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