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The increasing order of the following compounds towards HCN addition is :

(1) (iii) < (i) < (iv) < (ii)

(2) (i) < (iii) < (iv) < (ii)

(3) (iii) < (iv) < (ii) < (i)

(4) (iii) < (iv) < (i) < (ii)

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Aldehydes,ketones and carboxylic acids, Chemical reactions of aldehydes and ketones

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Ans. (1) (iii) < (i) < (iv) < (ii)

Sol. –I, – M effect of NO2 increase reactivity towards nucleophilic addition reaction with HCN.

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